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Holder Manchester City will face FC Copenhagen in the last 16 of the Champions League.
Arsenal, the current Premier League leader, will take on Portuguese side, Porto in the first knockout round.
City played Copenhagen – who came through a group that included Manchester United – in the early stages last season, winning 5-0 at the Etihad Stadium and drawing 0-0 in Denmark.
Spanish champion Barca, meanwhile, was handed a tough assignment against Serie A winner, Napoli.
Real Madrid, the record 14-time winners, is paired with RB Leipzig with its city rival, Atletico facing Inter Milan.
Paris St Germain will play the fourth Spanish side in the draw, Real Sociedad, with the two German teams, Bayern Munich and Borussia Dortmund, tackling Lazio and PSV respectively.
